克拉苏构造带盐下超深层储层的构造改造作用与油气勘探新发现

塔里木盆地克拉苏构造带油气群下白垩统巴什基奇克组埋深超过6 000 m,储层基质渗透率低,裂缝普遍发育,构造对储层的改造作用明显,但博孜9井的勘探突破反映出不同区带间构造改造作用差异较大、非均质性极强,重新认识构造对储层的改造作用对于预测超深层储层、指导油气勘探生产具有重要的意义。为此,基于钻井取心、构造平衡恢复、裂缝充填物同位素测年、区块应力数值模拟等资料,结合流体包裹体、声发射古应力、铸体薄片等实验分析方法,从定性分析到定量计算、研究了克拉苏构造带油气群超深层储层的构造改造作用及其差异性。研究结果表明:①北部天山造山带及南部古隆起控制了该构造带储层的沉积格局及差异构造变形,形成巴什基奇克组储层"西薄东厚"的分布特征;②博孜区段古应力最小,构造变形主要为正向挤压、逆冲传播,局部井区为斜向压扭;③大北区段主要为斜向压扭,古应力较小,构造变形为逆冲叠置;克深区段古应力最大,构造变形主要为正向挤压、后缘逆冲抬升、前缘滑脱收缩;④差异构造变形使同一构造带不同构造变形样式的构造减孔量呈现出较大的差别,且控制了不同区段造缝期与成岩胶结的叠加影响、中晚期裂缝网络与油气成藏期的配置关系,加剧了储层的非均质性,是区段间产能差异的基础改造因素;⑤现今构造应力的大小及方向影响裂缝有效性,南部为强挤压应力区,背斜相对高部位裂缝走向与现今应力交角较小,裂缝有效性最好;⑥构造成岩环境决定了构造裂缝充填物的类型,北部区块以淡水—半碱水介质成岩环境为主,裂缝充填物类型为方解石,有利于对储层进行酸化压裂改造。     

半导体激光器辐照损伤效应实验研究进展

半导体激光器(LD)工作在空间辐射或核辐射环境中时,会受到辐照损伤的影响而导致器件性能退化。文章回顾了不同时期研制的LD(从早期的GaAs LD到量子阱LD和量子点LD)在辐照效应实验方面的研究进展,梳理了国际上开展不同辐射粒子或射线(质子、中子、电子、伽马射线)诱发LD辐射敏感参数退化的实验规律,分析总结了当前LD辐照效应实验方法研究中亟待解决的关键技术问题,为今后深入开展LD的辐照效应实验方法、退化规律、损伤机理及抗辐射加固技术研究提供理论指导和实验技术支持。     

Fabrication of Cu/graphite film/Cu sandwich composites with ultrahigh thermal conductivity for thermal management applications

Effective thermal management of electronic integrated devices with high powder density has become a serious issue, which requires materials with high thermal conductivity (TC). In order to solve the problem of weak bonding between graphite and Cu, a novel Cu/graphite film/Cu sandwich composite (Cu/GF/Cu composite) with ultrahigh TC was fabricated by electro-deposition. The micro-riveting structure was introduced to enhance the bonding strength between graphite film and deposited Cu layers by preparing a rectangular array of micro-holes on the graphite film before electro-deposition. TC and mechanical properties of the composites with different graphite volume fractions and current densities were investigated. The results showed that the TC enhancement generated by the micro-riveting structure for Cu/GF/Cu composites at low graphite content was more effective than that at high graphite content, and the strong texture orientation of deposited Cu resulted in high TC. Under the optimizing preparing condition, the highest in-plane TC reached 824.3 W·m⁻¹·K⁻¹, while the ultimate tensile strength of this composite was about four times higher than that of the graphite film.     

内热型超声雾化溶液再生系统最优内热量的研究

基于质量守恒、能量守恒定律，建立了内热型超声雾化溶液再生系统（IH-UARS）的再生性能预测模型并进行了充分的实验验证，通过研究不同内热量下IH-UARS的再生性能及其变化规律，寻求系统所需的最佳内热量并明确其可能的影响因素。结果表明：IH-UARS系统存在最优的内热量范围，使其再生系统性能最佳；所需最优内热量随着再生溶液流量增大呈显著的对数增长，但受空气流量的影响较弱；在该研究中的标准工况下，IH-UARS所需最优内热量约为275~350 W。此外研究发现：内热量的增长有益于促进初始浓度较高的溶液进一步浓缩再生，如当IH-UARS中内热量增至800 W时，其初始浓度为36%的溶液比24%的溶液浓度增量指标改善幅度高37%。研究所得结果可对提高溶液再生性能及经济性提供积极参考。     

聚硅酸氯化铝铁-聚丙烯酰胺处理生活污水的研究

以实验室自制的聚硅酸氯化铝铁(PSAFC)和助凝剂聚丙烯酰胺(PAM)为主要原料,复合处理高浊度的生活污水,利用正交法优化得出对生活污水混凝处理的最佳混凝条件。试验表明:在PAM和PSAFC的总投加体积2 m L、V(PAM)/V(PSAFC)为0.1、p H=5、反应温度25℃时,对生活污水的处理效果最好,絮凝率达到96.12%。对絮凝机理进行了探讨。     

A Thermodynamics Model for the Emergence of a Stripe‐like Binary SAM on a Nanoparticle Surface

It has been under debate if a self‐assembled monolayer (SAM) with two immiscible ligands of different chain lengths and/or bulkiness can form a stripe‐like pattern on a nanoparticle (NP) surface. The entropic gain upon such pattern formation due to difference in chain lengths and/or bulkiness has been proposed as the driving force in literature. Using atomistic discrete molecular dynamics simulations it is shown that stripe‐like pattern could indeed emerge, but only for a subset of binary SAM systems. In addition to entropic contributions, the formation of a striped pattern also strongly depends upon interligand interactions governed by the physicochemical properties of the ligand constituents. Due to the interplay between entropy and enthalpy, a binary SAM system can be categorized into three different types depending on whether and under what condition a striped pattern can emerge. The results help clarify the ongoing debate and our proposed principle can aid in the engineering of novel binary SAMs on a NP surface.     

经皮肝穿刺胆道腔内RFA术治疗恶性胆道梗阻安全性的研究进展

【摘要】 经皮经肝胆道引流（percutaneous transhepatic cholangiodrainage，PTCD）和自膨式金属支架植入术是目前公认的治疗无法手术切除的恶性胆道梗阻的有效方式，但胆道支架再狭窄明显影响疗效及预后。经皮肝穿刺胆道腔内RFA（percutaneous intraductal radiofrequency ablation）能够与胆道支架联合应用，延长胆道支架通畅时间，同时对狭窄段的局部肿瘤进行控制，提高恶性胆道梗阻的治疗效果。作为一种新的治疗方法，安全性尤其重要，本文就经皮肝穿刺胆道腔内RFA联合胆道支架治疗恶性胆道梗阻的安全性进行综述。